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91.
Jongmin Lee Hongji Yoon Kyoung Soon Choi Seungkyu Kim Sehun Seo Jaesun Song Byeong‐Uk Choi Jiseung Ryu Sangwoo Ryu Jihun Oh Cheolho Jeon Sanghan Lee 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(39)
To develop strategies for efficient photo‐electrochemical water‐splitting, it is important to understand the fundamental properties of oxide photoelectrodes by synthesizing and investigating their single‐crystal thin films. However, it is challenging to synthesize high‐quality single‐crystal thin films from copper‐based oxide photoelectrodes due to the occurrence of significant defects such as copper or oxygen vacancies and grains. Here, the CuBi2O4 (CBO) single‐crystal thin film photocathode is achieved using a NiO template layer grown on single‐crystal SrTiO3 (STO) (001) substrate via pulsed laser deposition. The NiO template layer plays a role as a buffer layer of large lattice mismatch between CBO and STO (001) substrate through domain‐matching epitaxy, and forms a type‐II band alignment with CBO, which prohibits the transfer of photogenerated electrons toward bottom electrode. The photocurrent densities of the CBO single‐crystal thin film photocathode demonstrate ?0.4 and ?0.7 mA cm?2 at even 0 VRHE with no severe dark current under illumination in a 0.1 m potassium phosphate buffer solution without and with H2O2 as an electron scavenger, respectively. The successful synthesis of high‐quality CBO single‐crystal thin film would be a cornerstone for the in‐depth understanding of the fundamental properties of CBO toward efficient photo‐electrochemical water‐splitting. 相似文献
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《Ceramics International》2020,46(9):13125-13132
It is of great significance to develop highly active and cost-effective electrocatalysts for the oxygen evolution reaction and hydrogen evolution reaction in alkaline solution. Herein, we report an interface engineering strategy to fabricate 3D hierarchical CuCo2O4@CuCo2S4 heterostructure catalysts with efficient synergistic effects for water splitting. Owing to the special nano-architectures with abundant active interfaces, the as-prepared CuCo2O4@CuCo2S4 catalysts exhibit superior electrochemical activity and prominent electrochemical stability, with a small overpotential of 240 and 101 mV for oxygen and hydrogen evolution reactions to deliver a current density of 10 mA cm−2, respectively. Remarkably, the CuCo2O4@CuCo2S4 materials directly applied as both anode and cathode electrode demonstrate excellent water splitting performance, achieving 10 mA cm−2 at a low cell voltage of only 1.53 V, outperforming the integrated state-of-the-art RuO2||Pt/C couple (1.56 V). Moreover, density functional theory calculations suggest that the excellent overall water splitting property of CuCo2O4@CuCo2S4 is attributed to a large amount of hierarchical hetero-interfaces, giving rise to effective adsorption and cleavage of H2O molecules on the catalyst surface. This work represents a general strategy to exploit efficient and stable hybrid electrocatalysts for renewable energy applications by rational catalyst interface engineering. 相似文献
94.
通过有限元仿真软件Autoform分析了热冲压过程中工艺参数的变化对22MnB5马氏体钢B柱起皱、回弹、减薄、马氏体量以及强度的影响。结果表明:22MnB5马氏体钢B柱热冲压最优化工艺参数为加热温度930 ℃,冷却速率80 ℃/s。该工艺参数下,热冲压过程各处均完成马氏体转变,硬度分布均匀,材料减薄率较低,热冲压成形效果好,尺寸精度高,冲压件强度均大于1400 MPa。 相似文献
95.
针对矿山现有的地质信息数据等,建立了以利用Surpac软件的三维地表模型、矿体模型及地质数据库,对矿山资源储量进行计算。基于地质统计学的理论,建立某铅锌矿地表模型、钻孔数据库、矿体模型、块体模型,对矿体内样品进行组合分析统计,采用幂次距离反比法对块体品位进行估值,最后根据国内对地质矿产资源的分类方法,按照不同边界品位、工业品位等分类依据,得出资源储量核实报告,为铅锌矿的后续生产,提供了可靠保证。结果表明:通过构建该矿地质数据库,建立的三维模型,可对地质工程、采矿工程、储量估算、矿石品位动态管理等提供技术支持。 相似文献
96.
The solvent-dependent polymorphism of the active pharmaceutical ingredient (API) carbamazepine is interpreted from calculations of the solid-state and API-solvent intermolecular interactions. These simulations suggested that apolar solute-solute interactions could be disrupted by apolar solvents. In contrast, the polar solute-solute interactions were found to be easily disrupted by polar and protic solvents. This is consistent with experimental observations that the crystallization of the metastable form II is more dominant in apolar solvents. The Mercury program remains the gold standard in terms of usability; however, further expansion into more complex simulation techniques could make this package of even greater use in pharmaceutical manufacturing workflows. 相似文献
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